Contrary to some
manufacturers’ claims, all carbons contain and leach phosphate.
Phosphate in carbon does not arise from phosphoric acid washing
of carbon, but from the organic material used to manufacture
the carbon. Acid washed carbons are washed with sulfuric or
hydrochloric acid, not phosphoric acid. Usually, carbons most
suited for water filtration (macroporous) leach the most phosphate.
Carbons designed for gas filtration (microporous) leach the
least. A few macroporous carbons available leach relatively
less because they have been pre-washed or acid washed to remove
soluble components.
Red
Slime
This one is simple. Do not use red slime killing products, usually
erythromycin. Aside from jeopardizing nitrification and denitrification,
antibiotics just kill off all susceptible strains of algae or
bacteria, then a few weeks later the resistant survivors take
over. Your slime killer stops working. The safest way to suppress
red slime is with light, specifically with the long UV available
in actinic sources. Increase the actinic light or other UV source
and remove any glass or thick acrylic between the light and
the water. UV sterilizers do not help with this because they
do not illuminate the aquarium.
“Berlin
System”
Finally, something else that keeps coming up. The new philosophy
is that if the nitrate concentration is too high, it is because
you have a too efficient nitrification filter. The solution
is to dismantle the wet-dry or other filter and start relying
solely on reef rock to do the job. Somehow, if you use reef
rock as your sole biological filter you will have a balance
between nitrification and denitrification.
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Somehow, all that
ammonia that is now being converted to nitrate will be processed
in some other mysterious way so as not to form nitrate. It has
been suggested that you don't even need a skimmer. Lots of reef
rock and that's it! Maybe some aquarists can make this work
for more than two weeks, but I do not think experimenting with
such a precarious—yes, precarious!—system (and that
is using the word loosely) is something to do unless you are
ready to gamble a lot of reef creatures and money. It has been
suggested that those who do not agree with this approach simply
do not understand the chemistry of reef rock. In all humility,
I have to admit I do not understand the mysterious new age chemistry
alluded to by some of the proponents of this approach. If you
have a high nitrate concentration, it makes more sense to find
a way to remove the nitrate, either by religious water changes
or some kind of denitrification filter or agent. If you have
too much nitrate, seek to improve the denitrifying capacity
of your rock and filter material, not short circuit your nitrifying
filter. Also, seek to remove ammonia before it is converted
to nitrite: a well vented wet-dry or ammonia tower can have
significant impact by venting free ammonia directly to the air;
also enhanced chemical filtration and skimming can remove many
amino-organics before they are bacterially converted to ammonia.
It is also important to consider that nitrate in itself is not
likely the real problem, but rather other not easily measured
impurities for which nitrate is a useful marker. All the more
reason not to neglect water changes and to consider supplemental
chemical, bacterial, and algal filtration.
Reef keeping is as much an art as it is a science. There is
no single best way to practice this art, but any approach should
be viewed with caution when it evokes the suspension of basic
chemical principles or plain good sense.
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